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Super Smash Bros. Obliteration features 105 Playable Characters in the game, which is by far the most in series history, Once all of the first 94/97 characters (not including the 6 downloadable, 3 Transformed,  or 3 amiibo ones based on the Mii Fighters from the previous game, which can be created) are unlocked, the Single Player Modes of All Star and Boss Battles are unlocked, in addition some stages can be unlocked by unlocking certain unlockable characters as well.

Starter and Unlockable Characters, Italics = Unlockable Character

Starter and Unlockable Characters
Mario
Mario Obliteration (18)
Mario Logo obliteration
Luigi
Luigi Obliteration (18)
Mario Logo obliteration
Peach
Peach Obliteration (18)
Mario Logo obliteration
Daisy
Daisy Obliteration (18)
Mario Logo obliteration
Captain Toad
Captain Toad Obliteration (18)
Mario Logo obliteration
Bowser
Bowser Obliteration (18)
Mario Logo obliteration
Bowser Jr.
Bowser Jr. Obliteration (18)
Mario Logo obliteration
Petey Piranha
Petey Piranha Obliteration (18)
Mario Logo obliteration
King Boo
KingBooNewIconO19
Mario Logo obliteration
Paper Mario 
Paper Mario Obliteration (18)
Mario Logo obliteration
Wario
Wario Obliteration (18)
Wario Logo Obliteration
Waluigi
Waluigi Obliteration (18)
Mario Logo obliteration
Ashley
Ashley Obliteration (18)
Wario Logo Obliteration
Rosalina @ Luma
Rosalina & Luma Obliteration (18)
Mario Logo obliteration
Geno
Geno Obliteration (18)
Mario Logo obliteration
Yoshi
Yoshi Obliteration (18)
Yoshi Logo obiteration
Donkey Kong
Donkey Kong Obliteration
DKSymbolObliteration
Diddy Kong
Diddy Kong Obliteration (18)
DKSymbolObliteration
Dixie Kong
Dixie Kong Obliteration (18)
DKSymbolObliteration
King K. Rool
King K. Rool Obliteration (18)
DKSymbolObliteration
Link
Link Obliteration (18)
Zelda Logo Obliteration
Zelda
Zelda Obliteration (18)
Zelda Logo Obliteration
Sheik
Sheik Obliteration (18)
Zelda Logo Obliteration
Ganondorf
Ganondorf Obliteration (18)
Zelda Logo Obliteration
Young Link
Young Link Obliteration (18)
Zelda Logo Obliteration
Toon Link
Toon Link Obliteration (18)
Zelda Logo Obliteration
Lana
Lana Obliteration (18)
Zelda Logo Obliteration
Midna
Midna Obliteration (18)
Zelda Logo Obliteration
Imp Midna
Imp Midna Obliteration (18)
Zelda Logo Obliteration
Skull Kid
Skull Kid Obliteration (18)
Zelda Logo Obliteration
Fox
Fox Obliteration (18)
Star Fox LogoObliteration
Falco
Falco Obliteration (18)
Star Fox LogoObliteration
Krystal
Krystal Obliteration (18)
Star Fox LogoObliteration
Wolf
Wolf Obliteration (18)
Star Fox LogoObliteration
Ice Climbers
Ice Climbers Obliteration (18)
IceClimberLogoObliteration
Samus
Samus Obliteration (18)
Metroid Logo obliteration
Zero Suit Samus
Zero Suit Samus Obliteration (18)
Metroid Logo obliteration
Dark Samus
Dark Samus Obliteration (18)
Metroid Logo obliteration
Inkling's
Inklings obliteration (18)
SplatoonLogoObliteration18
Olimar
Olimar Obliteration (18)
Pikmin SymbolObliteration
Kirby
Kirby Obliteration (18)
KirbySymbolObliteration
King Dedede
King Dedede Obliteration (18)
KirbySymbolObliteration
Meta Knight
Meta Knight Obliteration (18)
KirbySymbolObliteration
Bandana Dee 
Bandana Dee Obliteration (18)
KirbySymbolObliteration
Takamaru
Takamaru obliteration (18)
MurasameSymbolObliteration
Ness
Ness Obliteration (18)
EarthboundSymbolObliteration
Lucas 
Lucas Obliteration (18)
EarthboundSymbolObliteration
Isaac 
Issac obliteration (18)
GoldenSunLogoObliteration
Wonder Red 
Wonder Red Obliteration (18)
Wonderful101ObliterationLogo
Shovel Knight
Shovel Knight Obliteration
ShovelKnightObliterationLogo
Pikachu
Pikachu Obliteration (18)
Pokemon Symbol Obliteration
Charizard
Charizard Obliteration (18)
Pokemon Symbol Obliteration
Jigglypuff 
Jigglypuff Obliteration (18)
Pokemon Symbol Obliteration
Mewtwo 
Mewtwo obliteration (18)
Pokemon Symbol Obliteration
Decidueye
Decidueye Obliteration (18)
Pokemon Symbol Obliteration
Greninja 
Greninja Obliteration (18)
Pokemon Symbol Obliteration
Lucario 
Lucario Obliteration (18)
Pokemon Symbol Obliteration
Zoroark 
Zoroark Obliteration (18)
Pokemon Symbol Obliteration
Starfy
Starfy Obliteration (18)
StarfySymbolObliteration
Pac-Man
Pac Man Obliteration (18)
Pac ManObliterationSymbol
Duck Hunt 
Duck Hunt Obliteration (18)
Duckhunticon
Professor Layton
Professor layton obliteration (18)
ProfessorLayton ObliterationSymbol
Villager
Villager Obliteration (18)
AinmalCrossingSymbolObliteration
Excite Biker
Excite Bker obliteration (18)
Excitebike LogoObliteration
Balloon Fighter
Balloon Fighter Obliteration (18)
BalloonFightLogoObliteraion
Sonic
Sonic Obliteration (18)
Sonic Symbol Obliteration
Shadow 
Shadow Obliteration (18)
Sonic Symbol Obliteration
R.O.B. 
R.O.B. Obliteration (18)
R.O.B.SymbolObliteration
Shulk
SHulk obliteration (18)
XenobladeSymbolObliteration
Elma  
Elma Obliteration (18)
XenobladeSymbolObliteration
Captain Falcon
Captain Falcon Obliteration (18)
FZero Symbol Obliteration
Black Shadow
Black Shadow Obliteration (18)
FZero Symbol Obliteration
Dillon 
Dillon Obliteration (18)
BayonettaObliterationSymbol
Snake 
Snake Obliteration (18)
MetalGearSymbolObliteration
Bayonetta 
Bayonetta Obiteration (18)
BayonettaSymbolObliteration
Cloud 
Cloud Obliteration (18)
FinalFantasyObliteration
Pit
Pit Obliteration (18)
KidIcarusSymbolObliteration
Palutena
Palutena Obliteration (18)
KidIcarusSymbolObliteration
Dark Pit
Dark Pit Obliteration (18)
KidIcarusSymbolObliteration
Hades
Hades Obliteration (18)
KidIcarusSymbolObliteration
Marth
Marth Obliteration (18)
Fire Emblem Symbol Obliteration
Ike
Ike Obliteration (18)
Fire Emblem Symbol Obliteration
Black Knight 
Black Knight Obliteration (18)
Fire Emblem Symbol Obliteration
Lucina 
Lucina Obliteration (18)
Fire Emblem Symbol Obliteration
Robin
Robin Obliteration (18)
Fire Emblem Symbol Obliteration
Roy 
Roy Obliteration (18)
Fire Emblem Symbol Obliteration
Corrin 
Corrin Obliteration (18)
Fire Emblem Symbol Obliteration
Vyse 
Vyse Obliteration (18)
SkiesOfArcadiaSymbolObliteration
Shantae 
Shantae Obliteration (18)
Shantae ObliterationSymbol
Chibi-Robo 
Chibi Robo Obliteration (18)
ChibiObliterationSymbol
Little Mac
Little Mac Obliteration (18)
PunchOutObliterationSymbol
Ryu
Ryu Obliteration (18)
Street FighterSymbolObliteration
Simon 
Simon Obliteration (18)
CastlevaniaObliterationSymbol
Rayman
Rayman Onliteration (18)
RaymanSymbolObliteration
Mega Man 
Mega Man Obliteration (18)
MegamanObliterationSymbol
Bomberman 
Bomberman Obliteration (18)
BombermanObliterationSymbol
Mr. Game & Watch 
Mr. Game & Watch Obliteration(18)
Game&WatchSymbolObliteration



Downloadable Characters (Free DLC)

In addition to the 3 custom made and original 94 default and unlockable characters there are also 5 downloadable characters making the grand total 103, Each of these characters come from various franchises both inside and outside of Nintendo including Banjo-Kazooie, A.R.M.S., Ever Oasis, Final Fantasy, Metroid, and Tales of Symphonia, Each of these characters are Free DLC and automatically come with the stages upon downloading, See the Stage Page for more information.

Free DLC Characters
Sylux
Sylux Obliteration (18)
Metroid Logo obliteration
Ninten 
Ninten Obliteration (18)
EarthboundSymbolObliteration
  Banjo & Kazooie  
Banjo-Kazooie Obliteration (18)
BanjoKazooieLogoObliteration
Lloyd 
Lloyd Obliteration (18)
TOSSymbolObliteration
Spring Man 
Spring Man obliteration (18)
ARMSLogoObliteration


Amiibo (Custom) Characters

The final three spots that are available for players to create characters are createable, the characters can be designed in the Mii Swordfighter, Brawler or Gunner amiibo models, they can be custom made and named, go to the Character Creator Option in the character select screen to do so

Amiibo (Custom) Characters
Mii Brawler
Mii Brawler Obliteration (18)
SSBLogoObliteration
Mii Swordfighter
Mii Swordfighter Obliteration (18)
SSBLogoObliteration
Mii Gunner
Mii Gunner obliteration (18)
SSBLogoObliteration

Full Character Roster (With Character Icons)

Full Character Roster (With Character Icons)
MarioObliterationIcon
LuigiObliterationJPG
PeachOIcon
DaisyObliterationIcon
BowserOIcon
BowserJROIcon19
RosalinaIconO19
CapToadIconO19
AshleyIconO19
WarioIconO19
WaluigiO19Icon
PeteyiconO19
KingBooIconO19
PaperMarioIconO19
GenoIconO19
YoshiIconO19
DkIconO19
DiddyIcono19
DixieIconO19
King K. RoolIconO19
LinkIconO19
ZeldaIconO19
SheikO19Icon
GanondorfO19icon
MidnaIconO19
NewImpMIdnaIconO19
YLinkIconO19
TLinkIconO19
SkullKidIconO19
LanaIconO19
SamusIconO19
ZSuitSamusIconO19
DarkSamusO19Icon
KirbyIconO19
KingDededeIconO19
MetaKnightIconO19
NewBDeeIconO19
FoxIconO19
FalcoIconO19
KrystalIconO19
WolfIconO19
TakamaruIconO19
IceClimbersIconO19
IsaacIconO19
WonderRedIcono19
ShovKnightIconO19
Inkling'sIconO19
NessIconO19
LucasIconO19
OlimarIconO19
PikachuO19Icon
CharizardO19Icon
DecidueyeO2019SmashIcon
JigglypuffO19Icon
MewtwoIconO19
GreninjaO19Icon
LucarioO19Icon
ZoroarkO19Icon
DHIconO19
ProfLaytonIconO19
VillagerIconO19
ExciteBikerIconO19
BalloonFighterO19Icon
SonicIconO19
ShadowIconO19
R.O.B.IconO19
ShulkIconO19
ElmaIconO19
CaptainFalconIconO19
BlackShadowIconO19
DillonIconO19
SnakeSmashO19Icon
BayonettaSmashO19Icon
CloudIconSmashO19
PitSmashIconO19
PalutenaSmashIconO19
DarkPitSmashO19Icon
HadesSmashO19Icon
MarthSmashO19
LucinaSmashOIcon19
RobinIconO19
IkeSmashOIcon19
BlackKnightSmashOIcon19
RoySmashOIcon19
CorrinSmashOIcon19
StarfyIconO19
ShantaeIconO19
Chibi-RIconO19
VyseIconO19
SimonSmashIconO19
Pac-ManIconO19
RandomIconO19
LittleMacIconO19
RyuIconO19
MegaManIconSmashO19Icon
RaymanSmashIconO19
BombermanIconO19
RandomIconO19
GameWatchIconO19
BrawlerIconO19
RandomIconO19
RandomIconO19
RandomIconO19
SwordFighterIconO19
GunnerIconO19
Banjo-KazooieIconO19
LloydIconO19
SyluxIconO19
NintenIconO19
SpringManIconO19


Tier List Rankings (For Online And Competitive Play)

Tier Characters
TierSIconO18
BayonettaSmashO19Icon
CaptainFalconIconO19
MarthSmashO19
SamusIconO19
CloudIconSmashO19
SpringManIconO19
A IconTierO18
PikachuO19Icon
WolfIconO19
TLinkIconO19
TakamaruIconO19
ZSuitSamusIconO19
IsaacIconO19
RyuIconO19
RosalinaIconO19
IceClimbersIconO19
Banjo-KazooieIconO19
LucarioO19Icon
NewATierIconO18
ZoroarkO19Icon
GreninjaO19Icon
FalcoIconO19
SkullKidIconO19
SonicIconO19
RaymanSmashIconO19
OlimarIconO19
MetaKnightIconO19
DiddyIcono19
FoxIconO19
ShulkIconO19
SheikO19Icon
SnakeSmashO19Icon
BIconO19
IkeSmashOIcon19
GenoIconO19
DixieIconO19
YoshiIconO19
PitSmashIconO19
LloydIconO19
VillagerIconO19
ShantaeIconO19
DHIconO19
KrystalIconO19
MarioObliterationIcon
NessIconO19
LucasIconO19
LloydIconO19
KingBooIconO19
DarkSamusO19Icon
MewtwoIconO19
ZeldaIconO19
DillonIconO19
CTierIconO18
ShovKnightIconO19
DkIconO19
LinkIconO19
VyseIconO19
SimonSmashIconO19
LuigiObliterationJPG
PeachOIcon
Inkling'sIconO19
MegaManIconSmashO19Icon
NintenIconO19
HadesSmashO19Icon
RoySmashOIcon19
BowserJROIcon19
Pac-ManIconO19
DaisyObliterationIcon
BowserOIcon
CharizardO19Icon
NewImpMIdnaIconO19
DTierIconO18
SyluxIconO19
DecidueyeO2019SmashIcon
BlackShadowIconO19
King K. RoolIconO19
RobinIconO19
ProfLaytonIconO19
LanaIconO19
MidnaIconO19
DarkPitSmashO19Icon
ShadowIconO19
ElmaIconO19
CapToadIconO19
KirbyIconO19
BombermanIconO19
ETierIconO18
YLinkIconO19
ExciteBikerIconO19
BalloonFighterO19Icon
GanondorfO19icon
BlackKnightSmashOIcon19
R.O.B.IconO19
CorrinSmashOIcon19
WarioIconO19
AshleyIconO19
NewBDeeIconO19
PalutenaSmashIconO19
LittleMacIconO19
GunnerIconO19
BrawlerIconO19
FTierIconO18
GameWatchIconO19
StarfyIconO19
PaperMarioIconO19
WaluigiO19Icon
JigglypuffO19Icon
KingDededeIconO19
PeteyiconO19
SwordFighterIconO19

Character Unlock Criteria

Character How To Unlock
Daisy Score At Least 10 Consecutive Combos In Training With Any Character.
Captain Toad Complete Smash Mode With Either Peach Or Daisy On Any Difficulty, Without Continuing.
Bowser Jr. Clear Smash Mode On 4.0 Difficulty Or Higher With Bowser, Without Continuing.
King Boo Clear Smash mode with Luigi or Petey Piranha on 5.0 Difficulty or Higher Without Any Continues,

Or Play 350 Matches in Vs. Mode).

Paper Mario Hit Over 500 Ft. in Super Slugger Competition With Any Character.
Wario Beat Smash Mode on Any Difficulty With Any Character),

Or Play 10 Matches in Vs. Mode.

Waluigi Hit Over 1000 Ft. In Super Slugger Competition with any Character.
Geno Beat Target Smash With All Super Mario, Wario, and Yoshi Series Starter Characters
Dixie Kong Beat Smash Mode With Either Donkey Kong or Diddy Kong on 4.0 Difficulty Or Higher, Without Continuing.
King K. Rool Beat Event Match #8 "The New Day Heavyweights.
Ganondorf (Beat Smash Mode With Link Or Zelda on 5.0 Difficulty Or Higher, Without Continuing).
Young Link Beat Smash Mode, With At Least 10 Starter Characters, 2 Of Whom Must Be Link And Zelda.
Toon Link Beat 100 Man Obliteration With Any Character.
Lana Clear 45 Minute Obliteration with either Link or Zelda.
Midna/Imp Midna Play 300 Matches in Vs. Mode.
Skull Kid Play 425 Matches In Vs. Mode.
Falco Clear Smash Mode With Fox On Any Difficulty, Without Continuing.
Krystal Clear Event Match #23, "Distress Beyond The Lylat System".
Wolf Clear Smash Mode With Fox, Falco, And Krystal, On 6.0 Difficulty Or Higher, with No Continues.
Dark Samus Clear Smash Mode With Samus On A 6.0 Difficulty Or Higher, Without Continuing.
Inlkling's Clear 30 Minute Obliteration With Any Character
Meta Knight Clear Smash Mode With Kirby And King Dedede on 4.0 Difficulty Or Higher, Without Continuing.
Bandana Dee Clear Event Match #28 "Waddle Dee Siege".
Lucas Clear Smash Mode With Ness On 4.0 Difficulty Or Higher, Without Continuing.
Isaac Clear Smash Mode with 20 Starter Characters.
Wonder Red Clear Smash Mode With At Least 30 Starter Characters.
Jigglypuff Clear Smash Mode With Pikachu, Charizard, Or Decidueye On Any Difficulty, Without Continuing.
Mewtwo Beat Target Obliteration with all Starter Pokemon Characters in the Game,

Or Play 375 Matches In Vs. Mode.

Greninja Clear Smash Mode With Pikachu, Charizard, And Decidueye On 5.0 Difficulty Or Higher, Without Continuing.
Lucario Clear Event Match #36 "Channeling The Inner Aura".
Zoroark Clear Event Match #34 "Illusions Of Chaos".
Duck Hunt Play 100 Matches In Vs. Mode
Shadow Clear Event Match #17 "Ultamite Life Form".
R.O.B. Clear Smash Mode With All 40 Starter Characters.
Elma Clear 15 Minute Obliteration with Shulk.
Black Shadow Clear Event Match #5 "Becoming The Bull".
Dillon Score At Least 5 Consecutive Combos In Training Mode With Any Character.
Snake Play 200 Matches In Vs. Mode.
Bayonetta Play At Least 500 Matches In Vs. Mode.
Cloud Play 450 Matches In Vs. Mode.
Dark Pit Clear Smash Mode With Both Pit And Palutena On A 6.0 Difficulty Or Higher, Without Continuing.
Hades Clear 15 Minute Obliteration With Either Pit Or Palutena,

Or Play 350 Matches in Vs. Mode.

Black Knight Score At Least 1 Kill In Cruel Obliteration With Any Character.
Lucina Beat Event Match #14 "Sins Of My Father".
Roy Complete Smash Mode With Ike, Marth, and Robin On A 5.0 Difficulty Or Higher, Without Continuing.
Corrin Clear 20 Minute Obliteration With Any Character.
Vyse Score At Least 60 Kills In 3 Minute Obliteration.
Shantae  Play At Least 325 Matches In Vs. Mode
Chibi-Robo Clear 60 Minute Obliteration with Any Character.
Simon Clear Smash Mode with 22 Out Of 54 Unlockable Characters.
Rayman Clear Smash Mode with any Starting Character on 6.0 Difficulty or Higher, Without Any Continues,

Or play 150 Matches in Vs. Mode.

Mega Man Play 475 Matches In Vs. Mode.
Bomberman Clear Target Obliteration With All 40 Starter Characters.
Mr. Game @ Watch Clear Smash Mode With All 94/97 Starter and Unlockable Characters in the Game.

Photo Credits

I would personally like to credit and extend my thanks to Template:User/OwtheEdgehog for his letter images and module placement/layout, and for imges of the rankings for the tier list.