Starters[]
Secret[]
How to Unlock[]
Captain Falcon[]
Captain Falcon is unlocked by playing Special Smash five times, then fight Captain Falcon in Mute City.
Ness[]
Defeat 80 foes in Endless Smash, then fight Ness in Onett.
Tails[]
Complete Classic mode as Sonic, then fight Tails in Chemical Plant Zone.
Waluigi[]
Complete the event, "Great Rivals", then fight Waluigi in Choco Mountain.
Lucario[]
Complete Classic mode as any pokémon on an intensity higher than 3.0, then fight Lucario in Pokémon Stadium 2.
Charizard[]
Complete the event, "Pokémon Tournament", then fight Charizard in Pokémon Stadium 2.
Falco[]
Play 25 matches on a Star Fox stage, then fight Falco in Lylat Cruise.
Ganondorf[]
Create a custom stage and play on it, then fight Ganondorf in the Tower of Hera.
Palutena[]
Complete the event, "Chapter 6" on Hard mode, then defeat Palutena in Palutena's Temple. (Chapter 6 requires getting Dark Pit.)
Lucas[]
Complete Classic mode as Ness on an intensity higher than 5.0, then fight Lucas in the Devil's Machine.
Rosalina[]
Play 10 matches on the Comet Observatory as a Mario character, then fight Rosalina in the same place.
Dark Pit[]
Play the game for a combined total of 10 hours.