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Does to people's lack of interest to put their characters in this game, this game is renamed Super Sam Squad: Pokémon-Formation.
- Sam The Koopa. Transformed into: Marshtomp. (Starter)
- Fire John. Transformed into: Magmar. (Starter)
- Snivy. (1st recruited, become traitor after beaten Clarx)
- Starly. (2nd recruited)
- Lavitar. (3rd recruited)
- Kadabra. (4th recruited)
- Gallade. (Last recruited)
- Palkia and Manaphy (Temporary members, against Fire Arceus)
Certain members will evolve after beating specefic bosses.
- Mewanabe. A Mew himself. (Fasle Final Boss, 7th Boss)
- Blaziken. (1st Boss)
- Zoroark. (2nd Boss)
- Kyogre. (3rd Boss)
- Textreme. Transformed into: Genosect. (4th Boss)
- Clarx. Transformed into: Mewtwo. (5th Boss)
- Serperior (A traitorous hero, 6th Boss)
- Fire Arceus. (Final Boss, along with Reshiram and Victini, in order to fight him, you must beat all of other bosses, including optional bosses.)
- Milotic (Optional Boss)
- Lugia (Optional Boss)
- Fasle Sam and False John (Optional Boss)
- Victini (On Fire Arceus's side)
- Reshiram (On Fire Arceus's side)