Takamaru is a normal rarety Assist Trophy. Once summoned, he will rush towards any opponent he finds, slashing them with his sword. He will also throw some in the air and midair slash them, delivering great damage.
Toad is an uncommon rarety Assist Trophy. Once summoned, he will start throwing Poison Mushrooms, damaging players. If a player touches Toad, it'll do 5% damage.
Waluigi is an uncommon rarety Assist Trophy. Once summoned, he will jump around the stage, and will start stomping one of the opponets, and will hit them with his Tennis Racket.
Deoxys flies into the sky and uses Hyper Beam, which shoots a very powerful beam of light directly downards onto the field. He is a very rare Poke Ball.
Charizard uses Flamethrower to breathe a stream of fire alternatively left to right, but stays in one place. He provides good defense and is a common Poke Ball.